Enhanced Oxygen Isotope Determination in Uranium Oxides Using BrF5 Fluorination          下载免费PDF全文

Malorie Dierick  Éric Pili  Nelly Assayag  Pierre Agrinier 《Geostandards and Geoanalytical Research》2017,41(3):397-409

A new method for accurate determination of oxygen isotopes in uranium oxides encountered in the nuclear fuel cycle was developed using the conventional BrF₅ fluorination technique. Laser‐assisted fluorination was tested for comparison. We focused on fine powders of triuranium octoxide (U₃O₈), uranium dioxide (UO_2±x with 0 ≤ x ≤ 0.25), uranium trioxide (UO₃.nH₂O, with 0.8 ≤ n ≤ 2) and diuranates (M₂U₂O₇.nH₂O, with M = NH₄, Na or Mg_0.5 and 0 ≤ n ≤ 6). Fluorination at room temperature and heating under vacuum at 150 °C are shown to eliminate both adsorbed and structural water from the powder samples. Precision fit for purpose of δ¹⁸O values (± 0.3‰, 1s) and oxygen yields (close to 100%) were obtained for U₃O₈ and UO₂ where oxygen is only bound to uranium. A lower precision was observed for UO₃.nH₂O and M₂U₂O₇.nH₂O where oxygen is both present in the structural H₂O and bonded to uranium and where the extracted O_2(g) can be contaminated by NF₃ and NO_x compounds. Laser‐assisted fluorination gave shifted δ¹⁸O values between +0.8 and +1.4‰ for U₃O₈, around ?0.8‰ for UO₃.nH₂O and between ?3.9 and ?4.5‰ for M₂U₂O₇.nH₂O (± 0.3‰, 1s) compared with the conventional method.  相似文献   

Mechanisms of salinization in a middle Eocene lake in the Tanggu area of the Huanghua Depression     

《Marine and Petroleum Geology》2017

The Sha-3-5 Submember of the Shahejie Formation in the Tanggu area of the Huanghua Depression contains analcime-bearing dolomite, indicating salinization of an ancient lake during deposition. Solar evaporation and hydrothermal salinization have both been proposed as ways to generate these saline conditions. Based on a comprehensive analysis of core data, thin sections, spore and pollen data, elemental geochemistry, pyrolysis results, and vitrinite reflectance, we assessed the mechanisms driving salinization in light of provenance evolution, geothermal evolution, paleoclimate, mineral responses to evaporation, and the relationship between fluid temperature and salinity. The vertical profiles of ΣREE, Eu/*Eu, and T_max exhibit little variation, and the maximum paleotemperatures attained by organic matter are comparable to present-day drill hole temperature. No major changes in provenance or paleotemperature and no petrological fabrics that would indicate a hydrothermal input are observed in the studied section. However, evidence for a semi-humid to semi-arid climate, primary evaporitic textures and structures, and a positive relationship between fluid temperature and salinity all support evaporation as the primary mechanism driving rising salinity. Solar evaporation, rather than hydrothermal eruption, appears to have been the primary factor driving lake salinization during middle Eocene deposition of the dolomitic Sha-3-5 Submember.  相似文献   

CMIP3与CMIP5模式对中国西北干旱区气温和降水的模拟能力比较   总被引：2，自引：0，他引：2  

吴晶王宝鉴  杨艳芬常燕 陈林杨建才  刘新伟 《气候变化研究进展》2017,13(3):198-212

通过对15组CMIP3和CMIP5两代模式集合平均对中国西北干旱区气温和降水的模拟能力比较,发现CMIP5模式对气温和降水的模拟更接近观测值。CMIP5模式模拟年、春季、夏季、秋季平均气温的相关系数比CMIP3模式分别提升了0.15、0.13、0.24和0.02,冬季下降了0.07。CMIP5模式对西北干旱区的平均气温变化趋势的模拟效果比CMIP3有所提高,对年、春季、夏季、秋季、冬季趋势的模拟偏差比CMIP3分别减少了0.03℃/10a、0.10℃/10a、0.01℃/10a、0.06℃/10a、0.14℃/10a。对西北干旱区平均气温年、季的模拟偏差分布上,CMIP5模式的偏差均比CMIP3低1~2℃。但是天山区年、季节平均气温的模拟与整体模拟偏低情况相反,CMIP3和CMIP5分别偏高3~6℃和1~4℃,对夏季的模拟偏高最严重,分别达到6℃和4℃。CMIP5模式整体对西北干旱区降水量的模拟结果与观测值的平均相关系数与CMIP3相差不大,均不超过0.1,而且偏差仍然较大。CMIP5模式对西北干旱区的降水量的变化趋势模拟效果比CMIP3有所降低,对年、春季、夏季、秋季、冬季趋势的模拟偏差比CMIP3增加了0.67 mm/10a、0.23 mm/10a、0.51 mm/10a、0.11 mm/10a、0.14 mm/10a。CMIP5模式对年、春季、夏季、秋季和冬季的降水量模拟的均方根误差相比CMIP3分别减少77.6 mm、25.5 mm、25.0 mm、18.8 mm和13.9 mm。在空间上,CMIP5模式对年、季节降水模拟仍然偏高,但是比CMIP3有明显缓解;CMIP3和CMIP5模式对夏季天山区年降水量和夏季降水量的模拟也与大部分区域偏高的趋势明显相反,两代模式对夏季天山区的降水模拟均偏低50 mm左右。  相似文献   

2008年“威马逊”台风期间海上大气波导时空特征   总被引：1，自引：0，他引：1  

成印河  周生启  薛宇峰 《广东海洋大学学报》2012,(3):64-69

结合 MM5数值模拟结果、天气图和卫星云图,系统分析了2008年“威马逊”台风引起的大气波导特征.本次台风过程中发生的大都为悬空大气波导,位于台风涡旋之外的西北部,台风越近波导高度、强度、厚度越大;同时数值模拟表明陆地地形对海上本次大气波导形成具有一定影响.利用大气波导这一特殊大气层结可以很好的评估和预测电磁波传播和海上探测通信系统  相似文献   

武汉九峰地震台超导重力仪观测分析研究   总被引：9，自引：1，他引：8       下载免费PDF全文

韦进  李辉  刘子维  康开轩  郝洪涛 《地球物理学报》2012,55(6):1894-1902

连续重力观测和GPS的技术结合能够监测到物质迁移和地壳垂直形变之间的量化关系.和相对重力测量以及绝对重力测量技术相比,其避免了时间分辨率和观测精度低,无法精细描述观测周期内的物质迁移过程问题.本文利用武汉九峰地震台超导重力仪SGC053超过13000 h连续重力观测数据;同址观测的绝对重力仪观测结果;气压数据;周边GPS观测结果;GRACE卫星的时变重力场;全球水储量模型等资料,采用同址观测技术、调和分析法、相关分析方法在扣除九峰地震台潮汐、气压、极移和仪器漂移的基础上,利用重力残差时间序列和GPS垂直位移研究物质迁移和地壳垂直形变之间的量化关系.结果表明:在改正连续重力观测数据的潮汐、气压、极移的影响后,不仅准确观测到2009年的夏秋两季由于水负荷引起的约(6~8)×10^-8m·s^-2短期的重力变化.而且在扣除2.18×10^-8(m·s^-2)/a仪器漂移和水负荷的影响后,验证了本地区长短趋势垂直形变和重力变化之间具有一致的负相关性规律.同时长趋势表明该地区地壳处于下沉,重力处于增大过程,增加速率约为1.79×10^-8(m·s^-2)/a.武汉地区重力梯度关系约为-354×10^-8(m·s^-2)/m.  相似文献   

10个CMIP5模式预估中亚地区未来50 a降水时空变化特征          下载免费PDF全文

吴昊旻  黄安宁  何清  赵勇 《干旱区地理》2013,36(4):669-680

利用CRU月降水资料首先对参与IPCC第五次评估报告（IPCC AR5）的10个CMIP5模式对1951-2005年中亚地区年降水气候平均态、年际变率以及线性趋势等特征参数的模拟能力进行了系统评估,并选取具有较好模拟性能模式的未来预估试验结果作多模式集合平均预估未来50 a（2011-2060年）中亚地区在不同代表性浓度路径下降水量各特征参数的空间分布特征,结果表明：多数模式能够模拟出中亚地区年降水气候平均态、年际变率以及线性趋势的空间分布特征,同时发现中亚地区年降水量在过去50 a整体以轻微增加为主,趋势不显著。根据定量评估结果,从10个模式中选取4个具有较好模拟性能的模式结果做集合平均,同时利用历史回报试验数据进行检验,发现集合平均的模拟结果无论在量级还是高、低值中心的位置和范围与CRU资料非常接近。未来预估结果表明4种排放情景下4模式集合平均的中亚年降水在未来50 a增加较为明显,尤其在中国新疆南部（由低值区转变为高值区）。总体来看,未来50 a中亚降水增加趋势随着RCPs的增加而增加,且降水增加显著的区域随着RCPs的增加而明显增大。  相似文献   

Fast and slow responses of the North Pacific mode water and Subtropical Countercurrent to global warming     

Lixiao Xu  Shang-Ping Xie  Qinyu Liu 《中国海洋大学学报(英文版)》2013,12(2):216-221

Six coupled general circulation models from the Coupled Model Intercomparison Project Phase 5 (CMIP5) are employed for examining the full evolution of the North Pacific mode water and Subtropical Countercurrent (STCC) under global warming over 400 years following the Representative Concentration Pathways (RCP) 4.5. The mode water and STCC first show a sharp weakening trend when the radiative forcing increases, but then reverse to a slow strengthening trend of smaller magnitude after the radiative forcing is stablized. As the radiative forcing increases during the 21st century, the ocean warming is surface-intensified and decreases with depth, strengthening the upper ocean’s stratification and becoming unfavorable for the mode water formation. Moving southward in the subtropical gyre, the shrinking mode water decelerates the STCC to the south. After the radiative forcing is stabilized in the 2070s, the subsequent warming is greater at the subsurface than at the sea surface, destabilizing the upper ocean and becoming favorable for the mode water formation. As a result, the mode water and STCC recover gradually after the radiative forcing is stabilized.  相似文献   

基于CMIP5多模式集合资料的中国气温和降水预估及概率分析   总被引：4，自引：1，他引：3  

杨绚  李栋梁  汤绪 《中国沙漠》2014,34(3):795-804

选用国际耦合模式比较计划第五阶段（CMIP5）提供的30个全球大气-海洋耦合模式（AOGCMs）在典型浓度路径（RCPs）情景下气温和降水量的预估结果,采用扰动法,用站点观测资料作为气候背景场替代AOGCM模拟的气候平均,尝试校正气候预估结果的系统性偏差。通过集合方法,用概率的形式给出中国平均气温升高1 ℃,2 ℃和3 ℃以及降水量增加10%,20%和30%概率的空间分布,讨论了中国未来平均气温和降水量可能的变化。结果表明：经过扰动法处理后的气温和降水量预估集合保留了当前气候的局地信息。预估平均气温在中国均有上升,北方地区尤其是青藏高原地区变暖的程度大于南方地区,北方大部分地区平均气温升高的趋势为0.28 ℃/10a。在21世纪初,中国北方地区年平均气温升高1 ℃的可能性超过50%。到了21世纪末期,中国大部分地区平均气温升高2 ℃的可能性超过60%,新疆北部以及青藏高原南部地区气温升高3 ℃的可能性超过50%。预估中国降水量普遍增多,中国北方地区降水量增多的程度要明显大于江淮流域及其以南地区,尤其是西北地区降水量增多非常显著,降水量增多30%的可能性超过70%以上。  相似文献   

IPCC AR4多模式对中国地区未来40 a雪水当量的预估   总被引：3，自引：2，他引：1  

王芝兰  王澄海 《冰川冻土》2012,34(6):1273-1283

通过评估参加CMIP3计划的22 个GCM在20 世纪气候情景(20C3M)下中国地区雪水当量模拟能力的检验, 挑选出模拟能力较好的模式, 通过多模式集合方法, 对SEARS的模拟结果进行集合, 预估未来40 a雪水当量在中国地区的时空变化特征.结果表明: 在A1B情景下和B1情景下, 中国地区未来40 a雪水当量年际变化均呈减少趋势; 在A1B和B1情景下, 青藏高原地区、 华北平原地区、 长江中游地区及东北北部地区的雪水当量均呈减少趋势, 其中在昆仑山西段帕米尔高原地区减少最为显著, 其次为喜马拉雅山区和巴颜喀拉山东段地区.在中国北部的内蒙古高原地区、 云贵高原等部分地区的雪水当量则有所增加.总体上, A1B情景下比B1情景下雪水当量的减少更为明显. 2021-2050年雪水当量在青藏高原减少显著; 对于季节变化来说, 在秋冬季积雪的累积期, 雪水当量可能增加, 尤其在10-12月, 而在积雪消融的春夏季(2-6月)有所减少.  相似文献   

The prediction for seismicity trends of M≥8 in the world by analysis of seismicity patterns   总被引：1，自引：0，他引：1  

HUAN Sheng-mu  DONG Rei-yin 《四川地震》2014,(1):42-47

After completion of a study on predicting risky zones of earthquake of M≥8 for 1-3 years in the mainland of China,which was supported by Chinese Joint Seismological Science Foundation(D07018 and D08009),a further study was extended to that of greater magnitudes in the world.Based on the historical earthquake cases,we finished the research report,forecasting global earthquakes with magnitude more than 8.0 using the image analysis of seismicity.In this research report,we summarize 11 abnormal seismicity images for predicting earthquake of M≥8.0 around the world.In our research report,we predicted earthquakes of M≥8.0 from June 2009 to June 2014,the medium term predicting within 5 years period.Among these 5 predictive areas,three earthquakes occurred,which is Samoa M8.1 Earthquake on 29 September 2009,Talca M8.5 Earthquake on 27 January 2010,Chile,and Eastern Sendai M9.0 Earthquake on 11 March 2011,Japan respectively.Here we introduce the main items of the image analysis of seismicity and we predict three earthquakes and think that the image analysis of seismicity can be of help.  相似文献